As industries worldwide respond to increasing pressure to reduce carbon emissions and meet net-zero targets, corrosion protection technologies are also undergoing significant change. Cathodic protection (CP), long recognised as one of the most effective methods of preserving reinforced concrete and steel-framed structures, has traditionally relied on non-renewable materials and energy-intensive manufacturing processes.
A new generation of sustainable alkali-activated cementitious materials (AACMs), often referred to as geopolymers, is now being developed to reduce the environmental impact of CP systems while maintaining long-term durability and performance.
The approach centres on repurposing industrial waste streams from sectors such as steel production, mining and fossil fuel generation to create conductive cementitious materials capable of functioning as both repair mortars and cathodic protection anodes.
Moving beyond traditional cathodic protection materials
Conventional sacrificial anodes used in cathodic protection systems gradually corrode during service and cannot be recycled once consumed. Similarly, impressed current cathodic protection (ICCP) systems often depend on titanium substrates coated with rare earth metal oxides, materials associated with significant environmental and resource pressures.
At the same time, ordinary Portland cement remains a major contributor to global carbon emissions, accounting for approximately 8% of worldwide CO₂ output.
AACMs offer an alternative route. Produced through ambient blending rather than high-temperature processing, these materials can reduce carbon emissions by more than 90% when compared with conventional Portland cement production.
In addition to their sustainability benefits, AACMs demonstrate strong engineering performance, including high compressive and flexural strength, low shrinkage, excellent chemical resistance and fire resistance exceeding 1,200°C.
Conductive geopolymer anodes
One of the most significant developments is the use of conductive AACMs as cathodic protection anodes.
The highly alkaline nature of the material allows it to activate zinc galvanic anodes and support impressed current systems while also functioning as a structural mortar or concrete. The material can therefore be sprayed, cast, chased into bridge decks or applied within masonry joints, allowing it to integrate directly into repair and preservation strategies.
Laboratory testing demonstrated that the material could support protection current densities substantially higher than those typically required for reinforced concrete structures before acid generation became problematic.
This stability provides confidence for long-term use at lower operational current densities and supports the durability of the overall protection system.
Extending the life of existing structures
The technology has already been applied to several existing structures in both the United Kingdom and the United States.
Edinburgh parking structure
An underground parking structure in Edinburgh utilised a combination of repair strategies designed around condition assessment data and risk profiling.
Conductive geopolymer ICCP anodes were chased into parking decks and sprayed onto structural beams and walls, while galvanic zinc anodes activated by AACM mortars were incorporated into concrete repairs.
Additional areas were treated with surface-applied corrosion inhibitors before waterproofing systems were installed.
The entire structure was divided into 44 controllable cathodic protection zones, alongside additional monitoring zones used to assess corrosion inhibitor performance and future maintenance requirements.
The project aimed to extend the service life of the structure by at least 25 years while significantly reducing embodied carbon compared with demolition and reconstruction.
Masonry-clad steel frame buildings
The technology has also been adapted for transitional steel frame buildings dating from the early twentieth century.
These structures, commonly found in major cities, often suffer from corrosion of embedded steel sections concealed behind brick, stone or terracotta cladding. Corrosion products expand over time, causing cracking, displacement and eventual structural instability.
At a major property on Park Avenue in New York City, conductive anode systems were installed behind terracotta cladding to protect corroding steel elements at upper levels of the building.
The modular nature of the power, monitoring and control systems allows future expansion across additional areas of the structure as required.
Cathodic preservation in new construction
The article also highlights the advantages of incorporating cathodic protection during the construction phase itself.
In so-called cathodic preservation systems, modular anode units manufactured from sustainable AACM materials can be attached directly to reinforcement before concrete placement.
These units are interconnected through plug-and-play wiring systems linked to remote monitoring and control equipment. Concrete can then be cast in-situ or precast around the protected reinforcement.
Research suggests that incorporating cathodic protection at the point of construction can provide significantly enhanced durability and resilience throughout the structure’s intended design life.
Monitoring and service life management
A key aspect of the systems described is the integration of embedded corrosion monitoring technology.
Remote monitoring systems allow engineers and asset owners to track corrosion rates, assess protection performance and estimate future service life without requiring frequent site visits.
This continuous monitoring capability provides owners with measurable evidence of performance while also reducing maintenance-related travel and operational carbon impacts.
Conclusion
The development of sustainable conductive geopolymer materials represents a significant step towards decarbonising cathodic protection for the built environment.
By repurposing industrial waste streams into functional repair and protection materials, these systems offer the potential to reduce embodied carbon, preserve existing structures and support long-term infrastructure resilience.
The projects highlighted demonstrate that sustainable cathodic protection systems can provide effective corrosion control across a range of reinforced concrete and masonry applications while contributing to broader environmental and net-zero objectives.
Combined with integrated remote monitoring and service-life assessment technologies, such systems may form an increasingly important part of future asset management and structural preservation strategies.